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Comprehensive resource exploring a unique chemical transformation that generates new compounds with diverse properties for modern organic synthesis research
Denitrogenative Transformation of Nitrogen Heterocycles explores all 10 polynitrogen heterocycles that are known to undergo denitrogenative transformations to date. Following highlights on the remarkable modifications encountered in the synthesis of nitrogen heterocycles, the chapters use a reaction-based approach to explain denitrogenative transformations in detail.
This book covers the exponential growth in scientific literature in the last few decades for denitrogenative reactions of polynitrogen heterocycles which play a key role in natural products, medicinal chemistry, pharmaceuticals, biochemistry, and material sciences. This book also discusses denitrogenative cascade reactions, which accomplish powerful transformations from simple polynitrogen heterocycles to more complex molecules in modern synthetic chemistry.
Written by a highly qualified academic with significant experience in the field, Denitrogenative Transformation of Nitrogen Heterocycles covers sample topics including:
Transannulation of N-sulfonyl-1,2,3-triazoles with polar multiple bonds such as carbonyls and nitriles and non-polar multiple bonds such as alkenes, alkynes, and allenes.
Insertion of azavinyl carbenes to C–X/X–X bond, denitrogenative rearrangements of N-sulfonyl-1,2,3-triazoles, and denitrogenative transformations of NH- and N-fluoroalkyl-1,2,3-triazoles
Metal-catalyzed and metal-free denitrogenative transformations of pyridotriazoles and denitrogenative transannulation of benzotriazoles and thiadiazoles.
Denitrogenative transformations of tetrazoles and radical denitrogenative transformations of polynitrogen heterocycles.
The first book of its kind on the subject, Denitrogenative Transformation of Nitrogen Heterocycles is an essential reference for researchers and scientists working in organic chemistry, organometallic chemistry, and transition metal catalysis, as well as academics and industry professionals in related fields.
Synthesis of Diverse Nitrogen Heterocycles Explored in Denitrogenative Transformations
Transannulation of N-Sulfonyl-1,2,3-triazoles with Polar Multiple Bonds
Transannulation of N-Sulfonyl-1,2,3-triazoles with Nonpolar Multiple Bonds such as Alkenes, Alkynes, and Allenes
Transannulations of N-Sulfonyl-1,2,3-triazoles with Carbo/Heterocycles
Insertion of Azavinyl Carbenes to C—H/X—H Bond
Insertion of Azavinyl Carbenes to C—X/X—X Bond
Denitrogenative Rearrangements of N-Sulfonyl-1,2,3-triazoles
Denitrogenative Transformations of NH- and N-Fluoroalkyl-1,2,3-triazoles
Asymmetric Perspective on Denitrogenative Transformation of 1,2,3-Triazoles
Denitrogenative Transformations of 3-Diazoindolin-2-imines
Metal-Catalyzed Denitrogenative Transformations of Pyridotriazoles
Metal-Free Denitrogenative Transformation of Pyridotriazoles
Recent Development in Denitrogenative Transannulation of Benzotriazoles
Denitrogenative Transannulation of Thiadiazoles
Denitrogenative Transformations of Benzotriazinones and Related Compounds
Denitrogenative Transformations of 3-Aminoindazoles
Denitrogenative Transformations of Tetrazoles and Pyridotetrazoles
Radical Denitrogenative Transformations of Polynitrogen Heterocycles
Application of Denitrogenative Transformations in Synthesis of Natural Products