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This text explores the connections between different thermodynamic subjects related to fluid systems. In an innovative way, it covers the subject from first principles to the state of the art in fundamental and applied topics. Using simple nomenclature and algebra, it clarifies concepts by returning to the conceptual foundation of thermodynamics. The structural elements of classical and molecular thermodynamics of fluid systems presented cover, via examples and references, both the usefulness and the limitations of thermodynamics for the treatment of practical problems. This new edition explores recent advances in statistical associated fluid theories and contains creative end‑of‑chapter problems connecting the theory with real‑life situations. It includes new chapters on thermodynamics of polymer solutions and molecular thermodynamics and also presents advances in the study of the activity of individual ions.
Provides a concise structure of concepts, using simple nomenclature and algebra.
Clarifies problems usually overlooked by standard texts.
Features end‑of‑chapter problems to enhance the reader’s understanding of the concepts.
Includes diverse topics of interest to researchers and advanced students, including elements of statistical thermodynamics, models of solutions, statistical associated fluid theory and the activity of individual ions.
Offers four appendices giving step‑by‑step procedures and parameters for direct use of the PRSV equation of state and the ASOG‑KT group method for fugacity and activity coefficient calculations.
Features a complete set of solutions to problems throughout the book, available for download on the book’s webpage under "Support Material".
This textbook is written for advanced undergraduate and graduate students studying chemical engineering and chemistry as well as for practicing engineers and researchers.
Fundamentals
Basic Concepts and Definitions
The First and Second Laws of Thermodynamics
Conservation of Energy in an Open Flow System: Definition of Enthalpy
The Algebra of State Functions: The Helmholtz and Gibbs Functions
Calculation of Changes in the Value of Thermodynamic Properties
Mixtures
Partial Molar Properties and Property Changes by Mixing
The Chemical Potential and the Gibbs–Helmholtz Equation
The Principles of Physical and Chemical Equilibrium
The Phase Rule and Duhem’s Theorem
Generality of the Thermodynamic Treatment for More Complex Systems
Ideal Gas and Ideal Gas Mixtures
Equilibrium in Terms of Fugacity and Activity
Calculation of Fugacities from Equations of State
Fugacity of a Mixture and of Its Components
Fugacities, Activities, and Activity Coefficients in Liquid Mixtures of Nonelectrolytes
Activity Coefficients and Excess Properties
Mixture Behavior, Stability, and Azeotropy
The Thermodynamics of Aqueous Electrolyte Solutions
The Thermodynamics of Polymer Solutions
Applications
Applications of Polymer Solution Thermodynamics
The Thermodynamics of Chemical Reactions
The Thermodynamics of Equilibrium‑Based Separation Processes
Heat Effects
Adsorption of Gases on Solids
Special Topics
Thermodynamics of Flow of Compressible Fluids
Elements of Statistical Thermodynamics
Statistical Thermodynamics Basis of Equations of State
Statistical Thermodynamics Justification of Some Commonly Used Expressions for the Excess Gibbs Energy
Statistical Thermodynamics Approach to the Generalized van der Waals Theory: Toward Understanding of the Molecular Behavior of Fluids
Generalized Lattice‑Fluid Model
COSMO‑RS‑Type Models
Thermodynamics of Hydrogen Bonding
The Family of SAFT Equation‑of‑State Models
The Activity of Individual Ions—Past, Present and Future: In Memory of Dr. Dan Fraenkel, April 1, 1946–March 8, 2023