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Polar Organometallic Reagents provides a critical overview of developments in the field of modern polar organometallic chemistry. With a particular focus on the emergent area of synergic heterometallic reagents, this timely volume describes our attempts to understand recently developed polar organometallics and their application in a range of new directions. Contributions from leading researchers present new synthetic work and discuss recent advances in characterization techniques, synthetic applications, and mechanistic understanding of heterometallic complexes.In-depth chapters provide detailed information on fundamental, structural, and theoretical aspects of polar organometallic chemistry while articulating the need and rationale for the advent of new reagents. Topics include alkali and alkaline earth organometallics, synergy and cooperativity, cationic p-block clusters and other developments in main group catalysis, synthetic trends in alkenyl copper, ate complex and borylmetal chemistry, non-traditional reaction environments, and trends in developing greener processes.Polar Organometallic Reagents is essential reading for researchers in chemical disciplines including synthetic inorganic and coordination chemistry, main group chemistry, organometallic chemistry, organic synthesis and catalysis.
The Road to Aromatic Functionalization by Mixed-metal Ate Chemis
Structural Evidence for Synergistic Bimetallic Main-Group Bases
Turbo Charging Group 2 Reagents for Metathesis, Metalation, and Catalysis
Mechanisms in Heterobimetallic Reactivity: Experimental and Computational Insights for Catalyst Design in Small Molecule Activation and Polymer Synthesis
Cationic Compounds of Group 13 Elements: Entry Point to p-block for Modern Lewis Acid Reagents
Recent Development in the Solution Structural Chemistry of Main Group Organometallics
Chemistry of Boryl Anions: Recent Developments
Novel Chemical Transformations in Organic Synthesis with Ate Complexes
Isolable Alkenylcopper Compounds: Synthesis, Structure, and Reaction Chemistry