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Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks imaging agents and probes in biomedicine and materials science for medicinal antioxidant applications and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.
A Brief History and Outlook of Nitroxides
General Approaches to Synthesis of Nitroxides
The Application of Nitroxides in Organic Synthesis
Spin Probes and Imaging Using Nitroxides
Nitroxides in Battery-related Applications
Computational Tools for Nitroxide Design
Nitroxide-mediated Polymerization
Nitroxides in Supramolecular Chemistry
Magnetism of Nitroxides
Applications of Nitroxide Spin Labels to Structural Biology
Nitroxides in Liquid Crystals
Nitroxide Intervention in Oxidative and Free Radical Damage in Biology and Disease
Spin Trapping
Biological Applications of Nitroxide Stable Free Radicals