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Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage between nitrogen and sulfur, selenium or tellurium atoms. Since the publication of A Guide to Chalcogen-Nitrogen Chemistry in 2005, the emphasis of investigations of chalcogen-nitrogen compounds has advanced from a focus on fundamental studies to the development of practical applications, as indicated by the title of this new edition. Pharmaceutical applications of organic sulfur-nitrogen compounds include drugs for the treatment of various diseases, as well as probes for locating tumour cells. From a materials perspective, carbon-containing chalcogen-nitrogen heterocycles have applications in everyday devices such as LEDs and solar cells. A new technology based on binary sulfur nitrides is being used for fingerprint detection in forensic science. As a result, this book includes seven new chapters and updates the others with extensive literature coverage of developments since 2005 while retaining earlier seminal results. This comprehensive text is essential for anyone working in the field, and the four introductory chapters emphasise general concepts that will be helpful to the non-specialist. The treatment is unique in providing a comparison of sulfur, selenium and tellurium compounds. Each chapter is designed to be self-contained, and there are extensive cross-references between chapters.
Introduction
Formation of Chalcogen-Nitrogen Bonds
Applications of Physical Methods
Electronic Structures
Binary Chalcogen-Nitrogen Neutral Molecules, Cations and Anions
Short-Lived Chalcogen-Nitrogen Molecules: Matrix Isolation
Acyclic S,N,O Anions and S-Nitrosothiols: Role in Biological Signaling
Chalcogen-Nitrogen Halides: Synthetic Reagents
Cyclic Chalcogen Imides: From Five- to 15-Membered Rings
Acyclic Organic Chalcogen-Nitrogen Compounds
Diamagnetic Five-membered Carbon-Nitrogen-Chalcogen Rings: From Fundamentals to Functional Devices
Diamagnetic Six-, Seven- and Eight-membered Carbon-Nitrogen-Chalcogen Rings
Paramagnetic Carbon-Nitrogen-Chalcogen Rings: Magnetic Materials
Metal Complexes of Carbon-Nitrogen-Chalcogen Radicals: Coordination Modes