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This book, with a foreword from Nobel Laureate Rudolph A Marcus, aims at introducing the reader to the Marcus theory of electron transfer reactions from a reading of excerpts of Marcus' papers. Notes from the author may be of help to the student or the beginner. Marcus' notes at the end of each paper, with his comments and remarks, are an invaluable supplement to his articles for students and scholars in the field of electron transfer reactions.
-Introduction
-Foundations of the Theory, Its First Formulation
-Extensions, Electron Transfer at Electrodes, Applications
-Theory of Electrochemical Electron Transfer
-Statistical Mechanical Theory of Electron Transfer, Equivalent Equilibrium Distribution, Reaction Coordinate for ET, Inverted Free Energy Effect, Interactions in Polar Media
-Unified General Theory of Electron Transfer Reactions
-Theory of Electron Transfer Reactions of Solvated Electrons and of Chemiluminescent Electron Transfer Reactions
-Rate Constants, Barriers, and Brønsted Slopes, Electron Transfer at Electrodes and in Solution
-Activated-Complex Theory, Application to Electron Transfer Reactions.
-Unusual Activation Parameters, Electron and Nuclear Tunneling, Mechanisms of Charge Separation, Spin Exchange and Electron Transfer in Photosynthesis.
-Mixed Reaction-Diffusion Rates, Quantum Effects in the Inverted Region, Frequency Factor in Electron Transfer.
-Entropic, Electrolyte, and Orientation.
-Dynamical Effects in Electron